Articles

Experimental Assessment of Guar Gum and Silicon Oxide Nanoparticle Hybrid for Enhanced Oil Recovery

/in /by

This study investigated the enhanced oil recovery (EOR) potential of hybrid formulations comprising guar gum polymer and silicon oxide (SiO₂) nanoparticles. The research aimed to address the limitations of using only polymer (Guar gum) as EOR agent, by exploring the synergistic effects of guar gum and SiO₂ nanoparticles in improving oil recovery efficiency.  The study involved core flooding experiments using Niger-Delta sandstone samples with different concentrations of guar gum and SiO₂ nanoparticles in both low-salinity (30,000 ppm) and relatively high-salinity (60,000 ppm). The results showed that the guar gum-SiO₂ nanocomposite formulations significantly outperformed the individual components in terms of oil recovery. The rheological analysis indicated that the inclusion of SiO₂ nanoparticles improved the viscosity and viscoelastic properties of the hybrid fluids, enhancing their mobility control capabilities.  Core flooding experiments demonstrated that the guar gum-SiO₂ nanocomposite formulations significantly outperformed the individual components, with the cumulative oil recovery rates reaching up to 83% in the low salinity condition of 30,000ppm and due to increase in salinity of 60,000ppm reduced recovery percentage of 79%. The study revealed that hybrid nanocomposites effectively mitigated permeability damage, a prevalent challenge associated with the use of polymers as enhanced oil recovery (EOR) agents. The incorporation of SiO₂ nanoparticles played a crucial role in preserving permeability by preventing the plugging of pore spaces, thereby enabling improved fluid flow and oil displacement.

Investigation of Nanoparticles Assisted Surfactant Flooding for Enhanced Oil Recovery Using Different Salinity Range

/in /by

Enhanced oil recovery (EOR) techniques are important for increasing oil production as to meet global energy demands. Surfactant flooding is a commonly used EOR method, but it has issues with surfactant molecules adhering on the surface of the reservoir rock more especially at higher salinity range. The study compares the effect of Sodium Dodecyl Sulfate (SDS) surfactant and Aluminum oxide (Al2O3) nanoparticle hybrid at different salinity concentration ratios, stand-alone Sodium Dodecyl Sulfate surfactant and Aluminum oxide nanoparticle on viscosity, salinity ranges of 30,000ppm and 60,000ppm, permeability change and oil recovery. The efficiency of the formulated fluids was tested through flooding experiment using different twelve core samples of Niger – Delta sand formation. The results showed that the surfactant-nanoparticle hybrid solution enhanced the viscosity of fluids, gave better permeability change and higher oil recovery for both 30,000ppm and 60,000ppm salinity change examined. Concentration ratio of 0.1 wt%Al2O3 and 0.3wt% SDS gave the highest cumulative oil recovery of 82.61% using 30,000 ppm and 78.26% for 60,000ppm brine concentration at the same fluid concentration ratio brine followed by 0.2 wt%Al2O3/0.3wt%SDS concentration ratio. The hybrid with 0.1 wt%Al2O3 and 0.3wt% SDS concentration ratio gave lower permeability change of 52.30md than every other concentration investigated. The combination of Aluminum oxide nanoparticle and Sodium Dodecyl Sulfate surfactant enhances surfactant properties as to improve displacement efficiency, reduce surfactant adsorption and permeability damage.

Laboratory Investigation on Permeability Change and Economic Analysis Using Some Selected Nanoparticles for Enhanced Oil Recovery

/in /by

Enhanced oil recovery using nanoparticles is an emerging technique that can potentially alter permeability and wettability of porous media for improved oil mobilization. This study experimentally investigates the permeability alteration caused by three commonly used nanoparticle types – copper (ii) oxide, zinc oxide and silicon oxide. Core flooding experiments were conducted on reservoir rock samples before and after treatment with nanoparticle dispersions. Results show decrease in permeability by 35% for copper (ii) oxide, 30% for zinc oxide and 10% silicon oxide respectively. Pore-scale analysis indicates that permeability change occurs through mechanisms like pore throat blocking/wettability alteration. Nanoparticle concentration is also found to influence the permeability variation, with optimal dosage. Among the systems tested, Silicon oxide is the most effective formulation for enhancing oil recovery applications based on its ability to recover oil with minimal alteration to formation permeability. From the result, Silicon oxide had a cumulative recovery of 17ml, 18.0ml and 18.5ml thereby generating a percentage recovery of 73.91%, 78.26% and 80.43%  while Zinc oxide had a cumulative recovery of 15.5ml, 18.0ml and 16.5ml thereby generating a percentage recovery of 77.50%, 78.26% and 71.74ml%, lastly Copper (ii) oxide had a cumulative recovery of 16.5ml, 17.0 and 16.0 generating a percentage recovery of 75%, 73.91% and 72.72% respectively with a concentration of 0.1%, 0.3%, and 0.5%. This study demonstrates the potential of Silicon oxide nanoparticles for enhanced oil recovery through permeability manipulation in porous media, however, the economic analysis shows that it’s quite expensive due to its cost of production and won’t be ideal for use. Hence Zinc oxide which also has a high volume of oil recovery, and less production cost can be used.

Laboratory Investigation on Enhanced Oil Recovery Using Local Alkaline –Polymer for Niger – Delta Region

/in /by

Approximately sixty percent of crude oil still lay trapped in the reservoir even after primary and secondary recovery processes have been completed, hence the need for a method that further improves recovery. To increase oil recovery and encourage utilization of local content, locally source alkaline and polymer materials were used to improve oil recovery in this study. The local alkaline and polymer used are plantain peel ash and corn starch respectively. The efficiency of the plantain peel ash and corn starch solution were tested using different seven core samples. The core samples were individually flooded with brine (salt and water) for secondary recovery process and different concentrations of plantain peel ash and corn starch both in stand-alone and in combined form were used for tertiary recovery. The results obtained from the experimental work showed that sample-B5 with 0.2g of plantain peel ash and 0.2g of corn starch in 100ml of brine gave the highest cumulative recovery of 86% as to compare to samples B1 and B2 which has the cumulative recovery of 70% and 78% respectively. Sample-B7 which has the highest concentration of corn starch (0.4g/100ml) gave the lowest recovery of 65% due to polymer adsorption on the rock surfaces which alters the rock wettability. The assessment of formation damage was done by evaluating and determining the permeability change after tertiary flooding. The concentrations with plantain peel ash have reduced permeability change. These locally sourced materials can replace synthetic enhanced oil recovery (EOR) chemical when properly modified and refined, and they are also cheap and environmentally friendly.

 

Improving Oil Recovery Efficiency Using Corn starch as a Local Polymer for Enhanced Oil Recovery Processes

/in /by

Polymer flooding is a chemical enhanced oil recovery method that improves the recovery of oil by controlling the mobility of water to oil phase. It uses polymer solutions to increase the viscosity of the displacing water thereby decreasing water/oil mobility ratio (Speight, 2013). The volumetric and displacement sweep efficiencies are positively affected by polymer flooding. The viscosity of the aqueous phase is increased due to the molecular size and structure of the polymer used. The main objective of this research was to study the ability of cornstarch (local polymer) to recover additional oil after conventional water flooding. The objective was successfully achieved by injecting four different unconsolidated samples (sand pack) with cornstarch solution at varying concentration of 500ppm, 1000ppm, 3000ppm, and 9000ppm. From the results of the experiment conducted, it was deduced that Cornstarch has the ability to recover an additional volume of oil about half the volume of oil recovered during conventional water flooding (i.e. if 50% of oil initially in place was recovered during water flooding, cornstarch can recover an additional 25% of the residual oil after water flooding). Also, higher concentrations of cornstarch reduce the recovery factor due to polymer adsorption on the rock surfaces which alters the rock wettability. To reduce the adsorption effect of Cornstarch, it is recommended that the concentration of Cornstarch be measured after the flooding experiments for a better understanding of the adsorption mechanism of cornstarch.