Abstract :
The formation of a composite nitride layer in an ammonia atmosphere with the addition of carbon– and oxygen–containing gases during gas nitriding is considered. The conditions for the formation of cementite during nitriding of steel and the influence of carbon in the matrix on the release of cementite are given. After oxidation of the nitride layer, modified nitride compositions with stable gradient structural–phase states were obtained.
Keywords :
carbonitride, cementite, corrosion lesions., diffusion nitride–oxide coating, nitride, oxycarbonitride, reactive diffusionReferences :
- Lakhtin Yu.M., Kogan Ya.D., Shpis G.I., Byomer Z. Theory and technology of nitriding. – M: Metallurgy, 1991. – p. 320.
- David Pye. Practical Nitriding and Ferritic Nitrocarburizing, ASM Publication, 2003. – p. 256.
- Zinchenko V.M., Syropyatov V.Ya. New possibilities of gas nitriding as a method of anticorrosion treatment of machine parts. // Metal science and heat treatment of metals. No. 7. 1998. – 2–6.
- Gerasimov S.A., Zhikharev A.V., Golikov V.A., Gress V.A., Zubarev G.I. Influence of preliminary heat treatment on the structure and properties of nitrided steels // Metal Science and Thermal Treatment of Metals. 2000. – No. 6. – p. 24–25.
- Petrova L.G., Aleksandrov V.A., Zharov G.M. Surface hardening of steels by methods of chemical–thermal treatment in multicomponent media. // Strengthening technologies and coatings, 2012, No. 6 (90). – p. 18–22.
- Kogan Y.D., Eshkabilov Kh.K. Oxynitriding of metallic articles. // Uproch. Tekhnol. Pokr. №6, 2006. – p. 10–
- Palček P., Mintách R., Nový F., Chalupová M., Marônek M. Change of fatigue characteristics of deep drawing sheets by nitrooxidation. // Chemické listy, Vol. 105, Issue 16 (2011). – p. 539–
- Petrova L.G., Aleksadrov V.A., Shestopalova L.P. Influence of pre–oxidation on the process of nitriding of steels containing chromium. // Bulletin of KhNADU. – Kharkov, 2008. – Issue. 46. – p. 82–85.
- Kh.Eshkabilov, Sh. Structure and properties of the modified diffusion nitride–oxide surface layer. E3S Web of Conferences 264, 05054 (2021). Conmechydro, 2021. 10.1051/e3sconf/202126405054.
- Lazar R., Marônek, Dománková M., Low Carbon steel treated by nitrooxidation process. // Strojastvo extra, 2007, No. 4. – p. 86–89.
- Kogan Ya.D., Solodkin G.A. Thermodynamic bases of controlled nitriding processes. // Metal science and heat treatment of metals, 1981, No. 4. – p. 16–20.
- Zinchenko V.M., Syropyatov V.Ya., Prusakov B.A., Perekatov Yu.A. Nitrogen potential: the current state of the problem and the concept of development. – M.: Federal State Unitary Enterprise Publishing House “Mashinostroenie”, 2003. – p. 90.
- Margulova T. X. The use of complexons in thermal power engineering. – M.: Energoatomizdat, 1986. – p. 280.
- Freiman M.I., Makarov V.A., Bryskin I.E. Potentiodynamic methods in corrosion research and electrochemical protection. – L.: Chemia, 1978. – p. 58.
- Eshkabilov Kh.K., Berdiev Sh.A. Controlled low alloy steel nitrooxidation technology. // International scientific and practical conference “World science”, “The goals of the World Science 2016”, January 27–28, 2016, Dubai, UAE. №2 (6), Vol.1. – p. 69–74.