Abstract :
This article used modern methods of physical and chemical analysis to study the properties of raw materials. In our studies, the chemical, mineralogical composition, physical and mechanical properties of ancient Khiva’s used historical monuments, ceramic bricks, and masonry mortars were studied. After studying these properties, we selected new formulations to develop alternative materials. We have studied the possibilities of using modifying additives, as a result of which an identical brick will be obtained in terms of color characteristics. During the research, the chemical, mineralogical and granulometric compositions of historical bricks, masonry mortars, and clay raw materials were determined, and their ceramic–technological and thermophysical properties were studied. The chemical composition of raw materials was studied by X–ray phase studies using non–traditional modern physical and chemical methods, the mineralogical composition of raw materials was determined by scanning (scanning) microscopy, and the granulometric composition of raw materials was determined by the dry method and sedimentation analysis. The raw materials for the development of materials for the restoration of architectural monuments were the loess–like rocks of the Suzanlinskoye deposit, waste from sugar production – defecation formed at the JV JSC “Khorezm Shakar” and amorphous silica. Loess–like rocks are predominantly light brown or gray in color, consisting of minerals that form a complex structure. According to the data obtained, a comprehensive study of loess–like rocks is of great scientific and practical importance, since more than 70% of the territory of the Republic of Uzbekistan is made up of loess–like and loess–like rocks.
Keywords :
Amorphous silica, Defecation, Granulometric composition, Loess loam, Restoration ceramic brick.References :
- S. Lesovik, L.K. Zagorodnyuk, Z.K. Babaev, Z.B. Dzhumaniyazov. “Analysis of the causes of brickwork efflorescence in the Aral Sea region”, Glas. Ceram., Vol. 77, Issue 7–8., 2020. – p. 277–279. 10.1007/s10717–020–00287–4.
- Ventol, M. Vendrell, P. Giraldez, L. Merino. “Traditional organic additives improve lime mortars: New old materials for restoration and building natural stone fabrics”, Constr. Build. Mater., Vol. 25., Issue 8., August, 2011. – p. 3313–3318. 10.10 16/J.CONBUILDMAT.2011.03.020.
- Lanas, J. I. Alvarez. “Masonry repair lime–based mortars: Factors affecting the mechanical behavior”, Cem. Concr. Res. Vol. 33, Issue 11., Nov, 2003. – p. 1867–1876. 10.1016/S0008–8846(03)00210–2.
- Jia, W. Chen, Y. Tong, Q. Guo. “Strength, hydration, and microstructure properties of calcined ginger nut and natural hydraulic lime based pastes for earthen plaster restoration”, Constr. Build. Mater., Vol. 323, March, 2022. 10.1016/j.conbuild mat.2022.126606.
- Moropoulou, G. Biscontin, A. Bakolas, K. Bisbikou. “Technology and behavior of rubble masonry mortars”, Constr. Build. Mater., Vol. 11, Issue 2., 1997. – p. 119–129. 10.1016/S0950–0618(97)07023–2.
- Pineda, S. Medina–Carrasco, A. Iranzo, L. Borau, I. García–Jiménez. “Pore structure and interdisciplinary analyses in Roman mortars: Building techniques and durability factors identification”, Constr. Build. Mater., Vol. 317, January, 2022. 10.10 16/j.conbuildmat.2021.125821.
- Elert, C. Rodriguez–Navarro. “Degradation and conservation of clay–containing stone: A review”, Construction and Building Materials, Vol. 330. Elsevier Ltd. – p. 1–16, May, 2022. 10.1016/j.conbuildmat.2022.127226.
- T. Oguchi, S. Yu. “A review of theoretical salt weathering studies for stone heritage”, Progress in Earth and Planetary Science, Vol. 8, Issue 1., Springer Science and Business Media Deutschland GmbH, 2021. – p. 1–23. 10.1186/s40645–021–0041 4–x.
- Ferrández, E. Yedra, C. Morón, A. Zaragoza, M. Kosior–Kazberuk, “Circular Building Process: Reuse of Insulators from Construction and Demolition Waste to Produce Lime Mortars”, Buildings, Vol. 12, Issue 2., February, 2022. – p. 1–25. 10.33 90/buildings12020220.
- Lokhova N.A., Makarova I.A. P.S. Firing materials based on microsilica / Lokhova N.A., Makarova I.A. P.S., 2002. – p. 163.
- GOST 21216–2014 Clay raw materials. Test methods // – 2015. – 43.
- GOST 9169–2021. Clay raw materials for the ceramic industry Classification // – 2021. – p. 21.
- Lesovik V.S., Strokova V.V., Volodchenko A.A. Influence of nanosized raw materials on the processes of structure formation in silicate systems // Bulletin of the Belgorod State Technological University named after. V.G. Shukhov. – 2010. – No. 1. – p. 13–17.
- K. Babayev, S.M. Masharipova, Musayev A.A, Ataeva F.A. “Waste from ceramic bricks, as a raw material for the production of restoration materials”, Int. J. Emerg. Trends Eng. Res., Vol. 8, Issue 8, 2020. – p. 4390–4393. http://www.warse.org /IJETER/static/pdf/file/ijeter56882020.pdf.
- GOST 212216.1–93. Clay raw materials / – Moscow: Publishing house of standards, 1993. – p. 7.
- Ovchinnikov N.L. Effect of mechanical activation of montmorillonite on the intercalation efficiency of polyhydroxyaluminumcations in the formation of pillar structure // Nanotechnolo.
- GOST 530–95. Brick and ceramic stones. – M.: Publishing house of standards, 1995. – p. 13.
- Budnikov P.P. Physical and chemical bases of ceramics / Budnikov P.P. – Moscow: Promstroyizdat, 1956. – p. 576.
- Babaev Z.K. Mechanical activation of loess–like loam and the possibility of producing high–quality bricks in the conditions of Uzbekistan Belgorod, 2019. – Part 1. – p. 11–17.
- Gurov N.G., Kotlyarova L.V. Expansion of the raw material base for the production of high–quality wall ceramics // Building materials, 2007. – p. 62–64.
- Gurov N.G., Naumov A.A. Ways to increase the frost resistance of semi–dry pressing brick // Building materials, 2012. – p. 40–42.
- Gurov N.G., Naumov A.A. Increasing the frost resistance of semi–dry pressed ceramic stone with a mineral modifying additive // Gurov N.G., Naumov A.A. Yu.A. // Building materials, 2012. – p. 78–80.
- Gurov N.G., Naumov A.A., Ivanov N.N. G.R. Patent RF 2455257. Ceramic mass / Gurov N.G., Naumov A.A., Ivanov N.N. G.R. – p. 4.
- Naumov A.A. Yu.A. Frost–resistant ceramic brick of semi–dry pressing from clay raw materials of the Shakhty plant / Naumov A.A. Yu.A. // Engineering Bulletin of the Don: Scientific Internet Journal, 2012. – p. 638–642.
- Zemnukhova L.A., Fedorishcheva G.A., Egorov A.G. Studies of the conditions for obtaining, composition of impurities and properties of amorphous silicon dioxide from rice production waste / Zemnukhova L.A., Fedorishcheva G.A., Egorov A.G. // Journal of Applied Chemistry, 2005. – p. 324–328.
- Zemnukhova L.A., Egorov A.G., Fedorishcheva G.A., Barinov N.N., Sokolnitskaya T.A. Properties of amorphous silica obtained from rice and oat processing waste // Zemnukhova L.A., Egorov A.G., Fedorishcheva G.A., Barinov N.N., Sokolnitskaya T.A. // Inorganic materials, 2000.